Method one: the hydrobromic acid to the metal cadmium, plus excess bromine water. When most of metal cadmium dissolve, leaching, not soluble cadmium, the filtrate obtained heating evaporation to close to saturation, at 0 degrees Celsius cooling crystallization, crystallization water through recrystallization, isolated is the four cadmium bromide hydrate. Under the condition of vacuum drying, the available water cadmium bromide.
Number two: put metal cadmium in quartz boat, in the heat resistant glass tube filled with dry nitrogen. Under the temperature of 450 ℃, with nitrogen gas through a containing Br2 washing bottle, take Br2 on quartz boat bromination reaction with Cd. Reacting to make 3 g metal cadmium completely, need about 2 h. If you want to improve the reaction temperature to speed the bromination reaction is not desirable, because the higher reaction temperature would have evaporated metal cadmium and products. When the product appeared for * * end of reaction. The CdBr2 in Br2 atmosphere distillation twice, and then melt CdBr2, with pure CO2 removal of excess Br2, cadmium can obtain anhydrous bromide.
Number three: CdBr2 · 4 h2o (see preparation method CdBr2 · 4 h2o) crystals in decompression drying in the dryer, containing potassium hydroxide can get anhydrous cadmium bromide.
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